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VOL. 23, NO. 1, 1ST QUARTER 2002

ALLCORR® ALLOY
ZIRCADYNE ZIRCONIUM
INTERGRANULAR CORROSION
HYDROMETALLURGICAL APPLICATIONS
EVENTS
INFO



ATI Introduces Corrosion Resistant ALLCORR® Alloy

By: Ron Gerlock and Andrea Van, Allegheny Technologies

Allegheny Technologies Incorporated introduces a corrosion resistant alloy, Allcorr® (UNS N06610). This fully austenitic, non-age hardenable nickel base alloy is designed to withstand highly corrosive environments.


Applications
The alloy, originally designed at Allvac, an Allegheny Technologies company, for use in the “sour” oil and gas industry, was found to be extremely corrosion resistant to a wide variety of corrosive environments. Allcorr® corrosion resistance coupled with its good strength, ductility and toughness make it a candidate for a wide variety of applications.
One example of a severe service application of the material is in the nuclear waste disposal industry. In the mid 1980s DuPont was responsible for material selection in the DOE’s Savannah River defense waste processing facility. In a testing program conducted by DuPont1, Allcorr® material was found to have superior corrosion resistance in the melter off-gas environment and was selected over C-276 and alloy 690 as the reference material for the off-gas quencher. While other materials were satisfactory for offgas system components maintained above the dew point, of the tested materials only Allcorr® alloy performed without pitting in the quencher where wetted conditions exist. Allcorr® material was the only material tested that resisted pitting and crevice corrosion at pH 1.6 and 90º C.


Savannah River Site Defense Waste Processing Facility remote view of vitrifcation melter pour spout.

According to Ken Imrich, Principal Engineer at Westinghouse Savannah River Company, who now operates the facility for the DOE, Allcorr® alloy has been in place in this application since March of 1993 without any problems. “Though ‘hot’ radioactive runs didn’t begin until March of 1996, the highly corrosive sodium chloride and sodium sulfate salts were present in the feed material since 1993 when ‘cold’ runs began,” explained Mr. Imrich.

Operating conditions of the quencher exhibit an inlet temperature of 350º C, while the outlet temperature is 90º C. Visual inspection of the inlet region and the center of the quencher, including several welds, was conducted in April 1995. During a second inspection, just before radioactive operations began in March 1995, the entire quencher was visually inspected. No evidence of general and localized corrosion was observed in either examination.

Deposits were collected during the latter inspection. X-ray diffraction (XRD) was used to identify the deposits, revealing sodium chloride and sodium sulfate from the inlet of the quencher, and only sodium chloride from the outlet. Ion chromatography was subsequently employed to measure the concentrations of the compounds in the inlet, showing just over 9,000 parts per million (ppm) chloride anions, and nearly 29,000 ppm sulfate anions.

Other potential severe service applications include sour gas wells. In 1991 a simulated deep sour gas well testing program evaluated alloys for suitability in that service. The test conditions closely resembled those of actual wells with 11 mol % hydrogen sulfide, 19 mol % carbon dioxide, elemental sulfur, chloride, at 425º F and at 9,500 and 10,300 psi. In addition to corrosion testing, the samples were subjected to autoclave testing using C-rings for evaluation of localized corrosion and environmental cracking resistance as well as slow strain rate testing. Under these conditions, Allcorr® material was one of only a handful of materials found to be truly resistant to environmental cracking and corrosion.2

With this kind of corrosion resistance, it’s little wonder fabricators are considering replacing competing alloys with Allcorr® material in a wide variety of applications and are eagerly requesting test material from Allegheny Technologies.


Corrosion Resistance

Allcorr® alloy is a nickel base alloy containing about 31% chromium, 11% molybdenum, and 2% tungsten. The very high chromium content allows the alloy to be exposed to very highly oxidizing environments without degradation. The molybdenum and tungsten help resist high chloride environments and low pH conditions. An extensive corrosion testing program3 performed by an independent laboratory compared a variety of corrosion resistant alloys in selected environments. These environments included pure acids, organics, mixed acids, and various salt solutions. The results show the Allcorr® material to have superior corrosion resistance to a higher number of environments than any of the other nickel base alloys compared (C-276, 625, G3, C4, B2, 600 and 825). An excerpt of test results comparing Allcorr® alloy and C-276 corrosion resistance in a selection of media is shown in Exhibit A. Allcorr® alloy was found to perform well in certain environments where zirconium does not, such as ferric or cupric chlorides. Allcorr® material was even found to have corrosion resistance comparable to tantalum in specific environments such as salts, certain oxides and organics, and sulfates.

Other published corrosion studies4 echo these findings, with Allcorr® alloy outperforming 625 and C-276 in numerous acid environments, including dilute nitric with small amounts of HCl, or HF and lower concentrations of formic acid over a range of temperatures.

Allcorr® alloy, like many of the nickel base materials tested in both cited studies, would not be recommended for high temperature, low concentration HCl service.


Mechanical & Physical Properties

Allcorr® alloy possesses good mechanical properties; with a typical room temperature yield strength around 50 Ksi (345 Mpa) and elongation above 50%. Typical impact properties exceed 240 ft-lb. (325 Joule) at room temperature. The alloy is easily cold worked, similar to other austenitic alloys, to enhance mechanical strength. The alloy was cold worked up to 70% without any loss of corrosion properties. Physical properties such as density, thermal expansion, and thermal conductivity are available upon request.


Weldability
Gas Tungsten Arc Welding (GTAW) and Gas Metal Arc Welding (GMAW) techniques, used for other commercially available nickel-base alloys, resulted in sound groove welds with good bead appearance, 100% joint efficiency, and excellent ductility. Fusion in both interpass and base metal/filler metal was complete and showed no tendency towards cracking. No deleterious second phases were apparent. There was no HAZ grain growth, no micro fissuring, and material fusion was complete in all areas.


Product Forms Availability
Through its operating companies, Allvac and Allegheny Ludlum, Allegheny Technologies can supply the Allcorr® material in a wide variety of product forms. Allcorr® alloy is readily hot worked and cold worked to produce a desired shape of form. The alloy is available in sheet, plate and strip from Allegheny Ludlum and in bar, billet, rod and coil from Allvac. The alloy’s excellent ductility and stable microstructure allow it to be formed into pipe, tubing, forgings, fittings and wire. With this variety of available forms, Allcorr® alloy is well prepared to serve the needs of the chemical process, oil and gas, and pollution control industries.




Specifications
Allcorr® material is covered by a full range of ASTM “B” specifications, as well as being qualified in NACE MR-01-75 up to 35 Rc hardness.

For test samples or more information on Allcorr® alloy and how it can be used to solve your severe service corrosion problems, please contact:

R. J. Gerlock
Allegheny Ludlum
Alabama & Pacific Avenues
Brackenridge, PA 15014
724-226-6231

or

D. DeRoner
Allvac
2020 Ashcraft Avenue
Monroe, NC 28110
704-289-4511


References
1. “ Material Selection for Defense Waste Processing Facility”. D. F. Bickford, and R. A. Corbett, International Conference on the Corrosion of Nickel Based Alloys, October 23-25, 1984, Cincinnati, OH, Joint American Society for Metals and International Nickel Co.

2. “Testing and Evaluation of Corrosion-Resistant Alloys”. B. D. Craig, et al, Materials Performance, Vol. 30 (12), December 1991, pp. 51-55.

3. “A Comparison of Corrosion Resistant Alloys in Severe Environments”. R. J. Gerlock, et al, Corrosion 85, Paper 166 NACE.

4. “Comparative Corrosion Resistance of Some High-Nickel, Chromium-Molybdenum Alloys”. R. A. Corbett, et al., Materials Performance, Vol. 28 (2), February 1989, pp. 56- 59.




 

Once Again Kemira Turns to Its Time-Tested, Corrosion Resistant Ally: Zircadyne® Zirconium

By: Kirk Richardson

Twelve years ago, Outlook ran a story on Kemira, an innovative chemical company in search of corrosion resistant materials for formic acid applications. As the story goes, years earlier Engineer Yrjö Santaholma happened across one of Wah Chang’s colorful, annodized zirconium coins at a chemical processing industry show.

Back home at Kemira in Oulu, Finland, the trinket reminded him of the unique metal as he and others searched for corrosion resistant materials that could withstand demanding processing environments. Glass-lined steel as well as graphite equipment and piping were experiencing frequent mechanical problems (including leaks and thermal cracks). Searching for a solution, Santaholma obtained zirconium samples, and put the metal to the acid test. The results were highly favorable. In fact, Zircadyne 702® alloy corrosion resistance in formic proved to be outstanding. Below the boiling point at 98% concentration and up to 250ºF and 70% concentration, the alloy’s corrosion rate was less than one mpy. Kemira immediately introduced Zircadyne 702® material into its Oulu plant, then specified the alloy for equipment in several other operations (as well as Oulu II unit) during the mid and late1980s.

Decades later, and zirconium is still the company’s material of choice in many applications. In fact, Kemira Chemicals Oy, which is currently expanding its formic acid production capacity from 60,000 to 80,000 mt/a (strengthening its position as the second largest producer in the world), is again depending on zirconium to hold corrosion in check in several critical plant operations. “During the plant’s 20 years of operation, the company has tested and used a wide variety of materials, ranging from high alloyed steels to elastomers, from graphite to glass linings, and special metals,” says Ilkka Pollari, Business Unit Manager. “We trust that now we manage the materials for formic systems quite well. For some hot formic acid-containing process stages, we prefer to use Zircadyne 702® or equivalent on wetted surfaces. This ensures high reliability and long service life, extremely low metal ion contamination of the processed products and, due to the innovative methods of fabrication, also cost efficiency.”

Such innovative fabrication methods include Kemira Engineering’s own novel ChemFace process for lining equipment with thin layers of corrosion resistant metals, such as zirconium. According to the company, its linings are fully resistant to shock and vacuum proof. Additional benefits include heat transfer characteristics (of the lining) that can be regulated by changing the bond area of the ChemFace welds. Kemira Engineering manufactures several major pieces of equipment with zirconium lining, including reactors and significant parts of distillation column systems. In addition, the workshop offers carbon steel vessels lined with titanium and tantalum.


Allegheny Technolodies' Tracy Ireland with Zr equipment destined for formic acid applications.



Cost- and time-efficient ChemFace is just one of many innovations the company has developed over the years. The Kemira of today is drastically different than it was when zirconium was first introduced in the early 1980s. The company produces hydrogen peroxide, peracetic acid and other chemicals required in the pulp-bleaching process, but bills itself as more than a “mere chemical supplier”. Kemira now offers what it calls “total bleaching solutions” as well as know-how backed by an R&D focus on oxygen-based chemicals-bleaching competence that it says “covers controlling every aspect of fiber surface reaction to add brightness, while retaining other optical and physical properties of pulp and paper.

Kemira’s main businesses are still chemicals, fertilizers and paints, but within those areas it has entered into several new businesses. Kemira is growing strongly in paper chemicals; earlier this year, it acquired Vinings Industries — one of the leading companies in USA. Another area of strong growth focus is chemical water treatment.

The formic acid business is also expected to grow significantly. Formic acid products are environmentally friendly replacements for more harmful and dangerous acids. Growth is expected in the replacement of antibiotics in animal feed.

Despite great progress though, one thing remains the same at Kemira: its commitment to zirconium as a corrosion solution to some of the company’s toughest processing challenges. It’s a solution that has withstood two decades of hot formic acid, freeing engineers to handle pressing problems, proving its value again and again.

For more information on Zircadyne® Zirconium, contact Wah Chang at 541-967-6977 or visit our web site at www.corrosionsolutions.com. For information about ChemFace linings “for the toughest of processes”, contact Kemira Engineering Oy at 358 10 86 1617 or e-mail
chemface.workshop@kemira.com.


 

Intergranular Corrosion

By: Kirk Richardson

The strangest things happen around research labs. Webster’s defines “fluke” as a stroke of luck. That’s how Wah Chang’s Gary Hanson describes a recent discovery he made using a Scanning Electron Microscope (SEM).

Jack Tosdale, Wah Chang’s Senior Corrosion Engineer, sent Hanson a badly corroded sample of Zirconium 702® alloy to analyze. The lab technician placed the material on a mount, secured with two-sided carbon “sticky tape”. After viewing and photographing the corroded sample, Hanson removed it from the mount and noticed residual left on the tape. “I was curious,” he says. “I was wondering what was left on the tape.” Hanson put the smudged mount back under the SEM at 1500x. What he saw surprised him. Amongst the residue, Hanson found an individual grain of zirconium, roughly 50 microns in width (see Figure 1) — a kind of diamond in the rough. “I didn’t realize that the intergranular corrosion had gone that deep,” he says. The corroded portion of the sample was bad enough that an individual grain had actually broken free.

The chance discovery also surprised Tosdale. He says that it’s not often that a single grain can be separated in its as-formed state from the rest of the microstructure. “It’s extremely rare to find that the grain boundary material has corroded, but not the grain itself,” he explains. In this case, the corrosion affected only the grain boundary constituents, mostly a Zr-Fe intermetallic. Tosdale is quick to point out that X-ray analyses of the surfaces on these grains (using the SEM; Figure 2) show the presence of iron on the surface — “probably there as an intermetallic compound of the zirconium and iron,” he says.


(F1) Individual grain of Zr as seen at 1500X. (F2) X-ray analyses reveal iron on the surface of these Zr grains.


A second look at the recrystallized grain (Figure 1) reveals the facets, which formed as a result of the metal being annealed after it was hot or cold worked. The recrystallization process tries to minimize the grain boundary surface area, according to Ron Graham, Director of Technology and Quality at Wah Chang. “The least surface area per unit volume solid shape is a sphere,” he says. “Spheres, however, cannot fill space without voids between the spheres. The tetrakaidodecahedron forms to minimize the grain boundary suface area while still filling 100% of space as grains nestle next to each other.”

Graham points out that the pits on the grain surfaces (right half of the grain) are likely due to the intersection of dislocations with the surface. These are known as dislocation etch pits. A dislocation is a defect in the atomic lattice structure. As such, it etches or corrodes at a higher rate than the surrounding defect-free zirconium. “Typically, dislocations can only be imaged by transmission electron microscopy, but in this case, we are seeing the trace of the dislocation because of its higher corrosion rate,” he says.

So in the final analysis, what might Gary Hanson’s micron-sized discovery mean to Wah Chang’s Corrosion Lab? According to Tosdale, “This (the picture) helps explain intergranular corrosion a little better. In this case, it helps you find out what in the grain boundary was attacked and what did the attacking.”

Graham sums it up. “This truly speaks to the phrase that ‘a picture is worth a thousand words.’”


 

Hydrometallurgical Applications of Titanium Clad Steel

By: J.G. Banker, Clad Metal Division, Dynamic Materials Corp.

Historically, pyrometallurgical processes have been the dominant methods for recovering many metals from their ores. These processes have tended to be both energy and pollution intensive. For many metals, newly developed hydrometallurgical processes provide a lower cost, cleaner alternative. These processes involve leaching the ores with aqueous solutions of common acids. Acid leaching processes have been proven commercially viable for extraction of copper, gold, nickel, uranium, molybdenum, zinc and other metals (Ref 1). These hydrometallurgical processes can range from relatively low-tech heap operations to more sophisticated high pressure acid leaching (PAL) processes.


Titanium clad autoclave for nickel laterite pressure acid pressure leaching. The autoclave is Titanium Grade 1 clad steel for the Murin Murin Nickel / Cobalt Project. Photo provided by the autoclave fabricator, ASC Engineering, Adelaide, Austrailia.


The aggressive acid environments of most leaching processes present significant corrosion issues. Low temperature-pressure processes, such as heap leaching, are commonly contained with plastics or other non-metallics. The high temperatures and pressures of the PAL operations require containment in metal pressure vessels, commonly called autoclaves. Corrosion issues necessitate that the autoclaves either be constructed of corrosion resistant alloys or be lined with ceramics or corrosion resistant alloys. Titanium has become the metal of choice for many PAL processes.
When pressures and/or temperatures and size demand very thick plate, the titanium equipment can become quite expensive. Titanium clad steel offers a reliable, cost effective alternative, providing durable titanium-lined equipment, which is lower cost than many less reliable alternatives. The explosion cladding process produces a high quality titanium-steel clad product with proven fabrication reliability and performance.

Titanium and titanium clad have been used in construction of PAL autoclaves since the 1950s. Reference 2 presents a list of test, pilot, and small production autoclaves constructed in the 1970s and 80s. It also presents information on use of titanium components in primarily refractory lined autoclaves dating back to the mid 1950s. Technology for pressure acid leaching of nickel from laterite ores was initially developed by Sherritt in the late 1950s at Moa Bay, Cuba (Ref 3). The Cuban facilities included extensive use of titanium and titanium clad components. The reliable performance of these units led to later use of titanium and titanium clad in subsequent larger production autoclaves.


Production Autoclaves for Nickel
In 1996 construction was begun on three production plants for pressure acid leaching of nickel in Australia. The plants required six PAL autoclaves. Design and project information is presented in Table 1. The operating temperatures are 250 to 260ºC, at pressures of 700 to 750 psi (4.8 to 5.2 MPa). The process includes sulfuric acid at around 5% concentration along with high levels of oxidizing ions. Titanium clad steel was selected as the material of construction. Weighing nearly 1,000,000 pounds each, these are the largest, heaviest titanium clad vessels that have been constructed to date. By early 1999, all six autoclaves were in operation. Three years later, operational performance of the titanium clad autoclaves is considered excellent (Ref 4), and maintenance costs are proving to be minimal. Current designs for future plants and modifications of the existing plants include application of titanium and titanium clad in additional plant equipment, including flash tanks and heat exchangers.




Materials Selection Considerations for Nickel PAL Autoclaves
Due to highly oxidizing conditions and low ph, titanium alloys and refractory brick are the materials of choice for corrosion performance. Currently accepted material options for construction for these autoclaves are solid titanium, titanium clad steel, and lead-lined steel with internal acid brick linings. Titanium clad steel construction offers many advantages.

In comparison to solid titanium:
1. For heavier wall vessels, titanium clad steel is considerably lower cost than solid titanium. Figure 2 presents a comparison of the costs of Ti Gr 17 clad steel clad vs. titanium Grade 12 plate for thicknesses ranging from 25 to 100 mm.

2. Fabrication costs for titanium clad steel are lower than for solid titanium in the thicknesses typical for autoclaves.

3. Components outside of the corrosion envelope, such as supports, stiffeners, agitator mounts and external jackets can be fabricated from low cost steel.

4. Since titanium is no longer the strength component, the titanium alloy can be chosen for features other than strength, such as corrosion resistance, erosion/abrasion resistance and/or ignition resistance.

5. The titanium cladding alloy selection can be varied selectively within the autoclave to provide unique performance features in specific regions of the autoclave.

In comparison to lead-brick designs:
1. Titanium provides excellent corrosion and abrasion resistance in direct contact with process media at the required operating temperatures and pressures, whereas lead does not. In order to maintain wall temperatures suitably low for lead membrane containment, internal brick linings are 300 to 500mm thick (12 to 20 in.) To maintain internal volume the vessel diameter must be larger, resulting in increased wall thickness, welding and fabrication costs, and transportation costs. Capital costs for the titanium clad option are projected to be 30% lower than acid-brick options (Ref 5).

2. Maintenance costs are much lower for titanium clad autoclaves.


Explosion Clad
Titanium clad steel is produced by the explosion cladding process. Explosion cladding is a solid state metal-joining process that uses explosive force to create a metallurgical bond between two metal components (Ref 6). Although the explosive detonation generates considerable heat, there is no time for heat transfer to the component metals; therefore, there is no appreciable temperature increase of the metals. The process is ideal for joining metals which are not compatible at high temperatures, such as titanium and steel. Explosion clad materials are typically supplied to equipment manufacturers in the form of flat plates and discs, formed heads, and cylindrical shapes. Titanium clad is normally produced to ASTM B898. For additional information on the explosion cladding process, visit www.dynamicmaterials.com.


Cost savings for Titanium steel clad vs. solid Titanium Grade 12 of thickness equivalent to steel. Clad is Ti Gr17 bonded to carbon steel. SA516 Gr70. Alternate cladding thicknesses of 4mm (0.16 in) and 8mm (1.32 in) are shown.


Titanium and Steel Alloy Options

All of the titanium alloys can be clad using the explosion bonding process. However, the optimum bond mechanical properties and optimum plate sizes are produced when the yield strengths of both the cladding and base metal are below 310 MPa (45,000 psi). Consequently the optimum bond strength and toughness of titanium cladding results from a combination of Titanium Grade 1, or similar, clad to a moderate strength pressure vessel steel, such as ASME SA516 Grade 70. (Titanium Grades 17, 11, and 27 exhibit similar yield strength and similar bond performance to Grade 1.) Although higher strength titanium alloys such as Grades 2, 7, 12 and 16, can be directly bonded to steel, the maximum sizes that can be manufactured reliably are too small for cost effective manufacture of PAL autoclaves. When cladding higher strength titanium grades in large plate sizes, it is common practice to use a Titanium Grade 1 interlayer between the alloy titanium and steel. References 7 and 8 discuss several of the currently available titanium alloys and highlight their specific features including cladability and relative cost of the clad product.


Titanium Clad Equipment Manufacture
Titanium clad equipment can be reliably constructed and has proven service reliability. Well over 1,000 titanium clad pressure vessels have been placed in service over the past 35 years. However, due to differences in metallurgical characteristics, thermal expansion, modulus, and other aspects, titanium clad construction is not “just another clad vessel.” Special considerations must be taken in design, fabrication, welding, and testing to ensure a reliable product. Inadequate attention to proper design and fabrication techniques can result in a subsequent vessel failure. Information on titanium welding and titanium clad fabrication, testing, and inspection procedures has been relatively broadly published (Ref 8,9).


Conclusion
Titanium clad solves corrosion, maintenance and environmental problems in many hydrometallurgical autoclave applications. Titanium clad construction permits autoclave designers a great deal of flexibility combined with significant cost reduction. Titanium alloys can be selectively applied in specific regions of the autoclave to maximize performance under anticipated localized environmental conditions at minimal cost. Explosion clad pressure vessel fabrication and performance have been demonstrated through three decades of experience. With proper attention to design, fabrication methods and testing, titanium clad equipment is highly reliable, durable, and long lasting.


References
1) Shutz, R.W., & Covington, L.C., “Hydrometallurgical Applications of Titanium” Industrial Applications of titanium and Zirconium, ASTM STP830, R.T.Webster & C.S.Young. American Society for Testing and Materials, 1984, pp29-47.

2) Banker, J.G., Forrest, A.L., “Titanium/Steel Explosion bonded Clad for Autoclaves and Reactors”, Proceedings of Randol Gold Forum ‘96, Randol Corp., Golden, CO, 1996.

3) Chalkley, M.E. et al, “The Acid Pressure Leach Process for Nickel Cobalt Laterite: A Review of Operations at Moa Nickel S.A.” Presented at Nickel Cobalt Pressure Leaching and Hydrometallurgical Forum, Perth, WA, May 13-14 ,1996.

4) O’Shea, J, Nickel Australasia, O’Shea & Assoc. Melbourne, Australia, Issue 28, Aug. 1999

5) Parkinson, G, “Leaching Metal...For All It’s Worth”, Chemical Engineering, Nov. 1999, pp 28-31.

6) Banker, J.G., Reineke, E.G., “Explosion Welding”, ASM Handbook, Vol. 6, Welding, Brazing, and Soldering, 1993, pp 303-305.

7) Schutz, R.W., “Recent Titanium Alloy and Product Developments for Corrosive Industrial Service,” National Association of Corrosion Engineers, Corrosion 95, Paper No. 244

8) Banker, J.G., Winsky, J.P, “Titanium/Steel Explosion Bonded Clad for Autoclaves and Vessels,” ALTA 1999 Autoclave Design & Operation Symposium, Alta Metallurgical Services, Melbourne, Australia, May 1999.

9) Titanium Welding Handbook and Video, International Titanium Association, Boulder, CO, 1994.

 

International CorrosionSolutions Conference

Coer d'Alene, Idaho • September 8 – 12, 2003

It’s more than a year away, but Allegheny Technologies Incorporated (ATI) is busy planning its Fourth International Corrosion Solutions Conference. The event will take place at the scenic Coeur d’Alene (Idaho) Resort September 8-12, 2003. ATI is now soliciting abstracts for the program (author, title, outline, and short summary).

Corrosion Solutions 2003 follows the successful 2001 conference that was held in Sunriver, Oregon. That event focused on design, fabrication, and maintenance of specialty steels, nickel alloys, niobium, tantalum, titanium, and zirconium processing equipment as well as other important corrosion-related topics. Corrosion Solutions 2001 featured 35 technical presentations, several excellent panel sessions, and included keynote speeches by Mr. Brian Fitzgerald of Exxon-Mobil Chemical and Mr. Sheldon Dean of Air Products.

The mission of the 2003 conference is to provide industry with the latest information on a variety of corrosion resistant materials, including specialty steels, nickel and other alloys, as well as niobium, tantalum, titanium, and zirconium. Topics of interest include case histories (successes and failures in aqueous corrosion prevention), maintenance/field service of equipment exposed to corrosive environments, fabrication breakthroughs and other issues (including welding and heat treating), materials research and development. Corrosive environments of interest range from chemical to mineral processing operations as well as salt water and other severe environments. Presentations should be technical in nature. Speakers will receive free registration, which covers the technical conference and selected events (a $595 value).

For more information, contact Sheryl Renzoni at 541-926-4211 ext: 6280 or e-mail sheryl.renzoni@wahchang.com. Submit abstracts for consideration to rick.sutherlin@wahchang.com. There are a limited number of sessions available, so please send proposed topics and background at your earliest convenience.

The 2nd Quarter 2002 issue of Outlook will provide detailed information for companies wishing to exhibit at Corrosion Solutions 2003.



Nitric Acid Producers Meeting & ANPSG Events Combined

Tucson, ArizonaOctober 7– 11, 2002

For the first time ever, this year’s Nitric Acid Producers Meeting and Ammonium Nitrate Producers Study Group (ANPSG) will be held during the same week at the same location. In the interests of cost and time savings as well as cross pollination of ideas, the executive committees from both groups agreed to a five-day format to be launched October 7-11 in Tucson, Arizona. Apache Nitrogen and Terra Nitrogen are the official meeting hosts.

Now for the details. ANPSG/Nitric Acid Producers 2002 will be held at the lovely Loews Ventana Canyon Resort. For early reservations, contact the hotel at 520-299-2020. The room block is limited and will be filled on a first-come, first-served basis. Attendees should mention that they are attending the ANPSG/Nitric Acid Producers Meeting to get the lower conference room rate.

Those interested in presenting at the meeting are encouraged to contact meeting chairs Ricardo Rodriguez of Nitrochem Corporation (613-348-3681 ext: 280) and/or Shawn Rana of Agrium USA (402-223-5271 ext: 291). Interested presenters should propose ideas early (these are subject to approval by the executive committee), as slots are limited.

Kirk Richardson of Wah Chang (541-967-6955) and Bob Gill of Ellett (641-941-8211) are coordinating vendor activities and associated evening events. Contact Sheryl Renzoni at 541-926-4211 ext: 6280 (or by e-mail at sheryl.renzoni@wahchang.com) if you would like information on exhibiting or are ready to sign up. As with everything else, the vendor hall offers limited table space, so exhibitors are encouraged to sign up early.

For updates on the meeting and conference events, check out ANPSG’s website at www.anpsg.org.



Welding

Albany, OregonJuly 23– 24, 2002 and August 13– 15, 2002

For those interested in boosting their welding IQ, Wah Chang is offering two summer sessions on welding that focus on working with zirconium, titanium, and titanium-niobium. This combination classroom/hands-on event takes place July 23-25 and August 13-15 in Albany, Oregon. The instructors recommend that participants have some experience in welding of stainless steel or aluminum. For more information, contact Sheryl Renzoni, Seminar Coordinator, at
541-926-4211 ext:6280 or e-mail her at sheryl.renzoni@wahchang.com.


 

LYNN DAVIS
President

PARRY WALBORN
Vice President, Commercial

GARY KNEISEL
Director of Sales

KIRK RICHARDSON
Editor


©2002 Wah Chang. Outlook is published quarterly by Wah Chang (Albany, Oregon office). The newsletter contains information on reactive and refractory metals, including hafnium, niobium, titanium, vanadium, and zirconium, as well as chemicals. The properties listed herein are average values based on laboratory and field test data from a number of sources. They are indicative only of the results obtained in such tests and should not be considered as guaranteed maximums or minimums.


Information & Order Contacts

Wah Chang
(headquarters)
P.O Box 460
Albany, Oregon 97321
Tel: (541) 926-4211
Fax: (541) 967-6990
www.wahchang.com
www.corrosionsolutions.com

Sales/Tech Support
Tel: (541) 967-6977
Fax: (541) 967-6994
E-mail: custserv@wahchang.com

CPI Service Center–U.S.
Tel: (541) 812-7038
Fax: (541) 967-6979
E-mail: starlene.ladd@wahchang.com

For information on agents/distributors of CPI products call: (541) 967-6906

For information on agents/distributors of nuclear-grade alloys call: (541) 967-6914

For information on agents/distributors of Ti, V, and Nb products call: (541) 967-6977

For information on Allvac products call: (704) 289-4511

For information on Allegheny Ludlum products call: (412) 394-2800