Search:

Specialty Metals That Make Our WorldTM
  Products
  CPI Zirconium
  Product Table
  Datasheets
    Zirconium:
  Zircadyne 702/705
  - in Chloride Solutions
  - in Nitric Acid
  - in Sulfuric acid
  - in Organic Applications
  Chemicals
  Machining & Forming Operations
    Hafnium:
  Chemicals
    Niobium:
  Niobium
  - C-103
  Machining & Forming Operations
    Titanium:
  Titanium Alloys
  Titanium Value Armor
  ATI 425 Titanium Alloy
  Titanium Bar & Wire
    Others:
  Silicon Tetrachloride
  Powder Metals
  Special Alloy Fabrication

 

GENERAL CORROSION DATA

Niobium, like other reactive metals, owes its corrosion resistance to a readily formed, adherent, passive oxide film. Niobium's corrosion properties resemble those of tantalum, although it is slightly less resistant in aggressive media such as hot concentrated mineral acids. Table 2 gives some typical corrosion data for niobium. Like tantalum, it is susceptible to hydrogen embrittlement if cathodically polarized by either galvanic coupling or by impressed potential. In addition to being stable, the anodic niobium oxide film has a high dielectric constant and a high breakdown potential. These properties, coupled with its good electric conductivity, have led to niobium's use as a substrate for platinum-group metals in impressed-current cathodic-protection anodes.

TABLE 2 - CORROSION DATA of NIOBIUM in AQUEOUS MEDIA
Solutions Concentration (Weight%) Temp. (°C) Corrosion Rate mm/y (mpy) *
Acid Solutions
Hydrochloric Acid 1 boiling nil
Hydrochloric Acid (aerated) 15 RT-60 nil
Hydrochloric Acid (aerated) 15 100 0.025 (1.0)
Hydrochloric Acid (aerated) 30 35 0.025 (1.0)
Hydrochloric Acid (aerated) 30 60 0.05 (2.0)
Hydrochloric Acid (aerated) 30 100 0.125 (5.0)
Hydrochloric Acid 37 RT 0.025 (1.0)
Hydrochloric Acid 37 60 0.25 (10)
Hydrochloric Acid 37% with Cl2 60 0.5 (20)
Hydrochloric Acid 10% with 0.1% FeCl3 boiling 0.025 (1.0)
Hydrochloric Acid 10% with 0.6% FeCl3 boiling 0.125 (5.0)
Hydrochloric Acid 10% with 35% FeCl2 boiling 0.05 (2.0)
  and 2% FeCl3    
Hydrochloric Acid 80% with 20% HNO3 30 0.025 (1.0)
Nitric Acid 30%+200 ppm F-1 80 0.125 (5.0)
Nitric Acid 30%+ 100 ppm F-1 80 0.125 (5.0)
Nitric Acid 30% +100 ppm F-1 80 0.025 (1.0)
Nitric Acid 50% + 50 ppm 80 nil
Nitric Acid 50 80 0.125 (5.0)
Nitric Acid 65 RT nil
Nitric Acid 65 boiling 0.025 (1.0)
Nitric Acid 70% + 200 ppm F-1 80 0.5 (20)
Nitric Acid 70% + 50 ppm F-1 80 0.025 (1.0)
NitricAcid 70%+100 ppm F-1 80 0.125 (5.0)
Nitric Acid 70 250 0.025 (1.0)
Phosphoric Acid 50 30 nil
Phosphoric Acid 50 90 0.125 (5.0)
Phosphoric Acid 60 boiling 0.5 (20)
Phosphoric Acid 85 30 nil
Phosphoric Acid 85 RT 0.0025 (0.1)
Phosphoric Acid 85 88 0.05 (2.0)
Phosphoric Acid 85 100 0.125 (5.0)
Phosphoric Acid 85 155 3.75 (150)

Page 6 of 34 Next

INDEX  •  CORROSION RESISTANCE PROPERTIES  •  FABRICATION   
NIOBIUM PRODUCTS     SPECIFICATIONS of NIOBIUM   
NIOBIUM ELECTRONICS APPLICATIONS